Structure and properties of pulsed-laser deposited carbon nitride thin films
2006
Carbon nitride (CNx) thin films were deposited on silicon (100) and (111) substrates at 300 -C by laser ablation of a graphite target using a pulsed Nd:YAG laser in a nitrogen atmosphere. The composition and structural properties of the films were investigated as functions of gas pressure and laser fluence. X-ray photoelectron spectroscopy (XPS) revealed a strong dependence of the amount of structurally incorporated nitrogen upon gas pressure. A maximum was observed at the highest laser fluence of 10 J/cm 2 and at an intermediate pressure of 4 Pa. Further analyses of the XPS N 1s core level spectra of the CNx films, exhibiting the highest elasticity in nanoindentation experiments, revealed a typical double-peak arrangement; most pronounced for the highest laser fluence at low pressures. These two peak components indicate that the nitrogen bonded onto a graphitic structure dominates over the two-fold coordinated pyridine-like bonding configuration. This favors the growth of intersecting corrugated graphene structures that may be considered to have ‘‘fullerene-like’’ microstructures. Additionally, Fourier Transformed Infrared Spectroscopy analyses of films deposited at different pressures show the presence of 2229 and 2273 cm 1 stretching peaks associated with CN triple bonds (CgN) of nitriles and isocyanides, 1640 cm 1 and 1545 cm 1 associated with the CfC and CfN and a peak at 1730 cm 1 ,
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