Triphenylmethyl tris(p-methoxyphenyl)phosphonium cation: a structurally characterized phosphonium analog of hexaphenylethane
2000
Reaction
of tris(p-methoxyphenyl)phosphine with [Ph3C][B(ArF)4]
[ArF=3,5-(CF3)2C6H3] afforded [Ph3CP(4-OMeC6H4)3][B(ArF)4], a structural analog of hexaphenylethane, which shows a very long P–C distance [1.931(3) A]
in the solid state, indicating
a strong steric repulsive interaction between the two parts of the phosphonium cation.
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