A Novel Stereoselective Photoinduced Intramolecular Cyclization of 1-(o-Allyloxyphenyl)-2-pentamethyldisilanyl Ethynes.

Sang Chul Shim,Seung Ki Park

A Novel Stereoselective Photoinduced Intramolecular Cyclization of 1-(o-Allyloxyphenyl)-2-pentamethyldisilanyl Ethynes.

2010

Sang Chul Shim
Seung Ki Park

Abstract Photolysis of 1-(o-allyloxyphenyl)-2-pentamethyldisilanyl ethynes 1a and 1b in benzene provides novel stereoselective intramolecular cyclization products 3a and 3b .

Keywords:

Organic chemistry
Stereoselectivity
Chemistry
Intramolecular force
intramolecular cyclization

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