Microplasma emission spectroscopy of carbon dioxide using the carbon monoxide Ångström system

The present paper describes a system and method for indirect emission spectroscopy of CO2 in the visible spectrum. This is achieved by using a microplasma spectrometer that first converts CO2 into CO and then measures emissions from the CO Angstrom system (B1Σ + → A1Π) at 560 nm. The experiments were performed on gaseous samples of CO2, mixed in both N2 and air, to concentrations between 0.01% and 100%. In addition to the microplasma spectrometer, the process was monitored by mass spectrometry with a residual gas analyzer. The CO2 to CO conversion efficiency was found to be very high, reaching a maximum of 41% at close to 100% selectivity. Furthermore, the CO Angstrom system was shown to facilitate excellent spectroscopic measurement of CO2 concentrations below 10%, with a linearity of R2 > 0.99 and an expected limit of detection in the parts-per-thousands range. The most promising aspect of the results was that the analysis was performed on extremely small total sample amounts where the gas flow through the systems was in the 0.1 µmole/s range. Hence, the present system has the prospect of filling a void in current sensor technology, where inexpensive and easy-to-use optical systems, such as nondispersive infrared sensors, cannot handle small sample amounts, while mass spectrometers, which can handle such samples, still are expensive, complex, and bulky.The present paper describes a system and method for indirect emission spectroscopy of CO2 in the visible spectrum. This is achieved by using a microplasma spectrometer that first converts CO2 into CO and then measures emissions from the CO Angstrom system (B1Σ + → A1Π) at 560 nm. The experiments were performed on gaseous samples of CO2, mixed in both N2 and air, to concentrations between 0.01% and 100%. In addition to the microplasma spectrometer, the process was monitored by mass spectrometry with a residual gas analyzer. The CO2 to CO conversion efficiency was found to be very high, reaching a maximum of 41% at close to 100% selectivity. Furthermore, the CO Angstrom system was shown to facilitate excellent spectroscopic measurement of CO2 concentrations below 10%, with a linearity of R2 > 0.99 and an expected limit of detection in the parts-per-thousands range. The most promising aspect of the results was that the analysis was performed on extremely small total sample amounts where the gas flow through ...