Chlorido(6-diphenyl­phosphino-2-pyridonato-κ2P,N)(6-diphenyl­phosphino-2-hydroxypyridine-κ2P,N)hydridoiridium(III) chloro­form 1.896-solvate

2007 
The title complex, [Ir(C17H13NOP)ClH(C17H14NOP)]·1.896CHCl3, contains hydride, chloride, 6-diphenyl­phosphino-2-hydroxy­pyridine (pyphosH) and 6-diphenyl­phosphino-2-pyridonate (pyphos) ligands coordinated to an IrIII metal centre to give a distorted octa­hedral coordination geometry. The two P and two N atoms of the pyphosH and pyphos ligands lie with a cis coordination in the equatorial plane. An intra­molecular O—H⋯O hydrogen bond is observed between the pyphosH and pyphos ligands.
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