Chlorido(6-diphenylphosphino-2-pyridonato-κ2P,N)(6-diphenylphosphino-2-hydroxypyridine-κ2P,N)hydridoiridium(III) chloroform 1.896-solvate
2007
The title complex, [Ir(C17H13NOP)ClH(C17H14NOP)]·1.896CHCl3, contains hydride, chloride, 6-diphenylphosphino-2-hydroxypyridine (pyphosH) and 6-diphenylphosphino-2-pyridonate (pyphos) ligands coordinated to an IrIII metal centre to give a distorted octahedral coordination geometry. The two P and two N atoms of the pyphosH and pyphos ligands lie with a cis coordination in the equatorial plane. An intramolecular O—H⋯O hydrogen bond is observed between the pyphosH and pyphos ligands.
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