Polymers and polymer building blocks from meadowfoam oil
2004
Abstract Meadowfoam oil methyl ester was metathetically cleaved with ethylene catalyzed by Re 2 O 7 –B 2 O 3 /Al 2 O 3 –SiO 2 + SnBu 4 or bis(tricyclohexyl phosphine) benzylidene ruthenium dichloride yielding α-olefins, α,ω-dienes and 5-hexenoic acid methyl ester as the main product. The corresponding ω-epoxy fatty acid ester was achieved by chemoenzymatic epoxidation with H 2 O 2 in the presents of Novozym ® 435. Glutaric acid mono methyl ester was synthesized by ruthenium-catalyzed oxidative cleavage with peracetic acid. Hydrocarboxylation with carbon monoxide/methanol yielded pimelic acid dimethyl ester. Metathetical dimerization of 5-hexenoic acid methyl ester yielded 5-decen-dioic acid dimethyl ester, which was subsequently polycondensed with ethylene glycole and 1,4-butanediol to high molecular weight polyesters. The ω-unsaturated ester was directly copolymerized with ethylene by an insertion-type palladium-catalyzed reaction to a high molecular weight functional polyolefin. The 5-epoxy hexanoic acid ester was polymerized to a comb like polyether.
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