Oxygen plasma effects on optical properties of ZnSe films

Zinc selenide is an infrared transparent semiconductor material being considered for use in space as an infrared optical coating. In this work, zinc selenide thin films of different thicknesses were exposed to an electron cyclotron resonance generated oxygen plasma, often used to “simulate” the low earth orbital environment. The maximum fluence used in our experiments was equivalent to ∼16 years in the low earth orbital environment. ZnSe thin film optical constants (both before and after oxygen plasma exposure) were determined using variable angle spectroscopic ellipsometry from the vacuum ultraviolet at 146 nm through the middle infrared to 40 μm. A parametric dispersion model (Herzinger–Johs) was successfully used to fit the optical data over the entire range from ultraviolet to infrared. Comparing the pre- and post-oxygen plasma exposure data, few changes were observed in the middle infrared region, while drastic changes were seen in the vacuum ultraviolet through visible to near infrared (0.73–8.5 eV)...