Study of the structure and electric quadrupole interaction in the intermetallic compound Hf2Fe

The electric quadrupole interactions at181Ta probe nuclei in a cubic Hf2Fe lattice were studied by the TDPAC method. In addition, the crystalline structure study of the Hf2Fe compound was performed. The results of the EQI measurement show the presence of two independent interactions, one at low frequency, characterized by ω Q (1) =33 Mrad/s and δ=30%, and the other at high frequency described by ω Q (2) =207 ± 2 Mrad/s and δ=4%. Both interactions are found to be compatible with the crystalline structure established in this investigation. The large temperature dependence of the electric field gradient of the second interaction in the range from 78K to 1183K was determined. The change in the EFG follows the empiricalT 3/2 -relation.