Boosting the electrochemical performance of MoO3 anode for long-life lithium ion batteries: Dominated by an ultrathin TiO2 passivation layer
2018
Abstract In this report, using atomic layer deposition (ALD) technique, TiO 2 layer with different thickness is conformally deposited on the surface of MoO 3 nanobelts for enhanced-performance anode. Impressively, the MoO 3 @85-TiO 2 (85 cycles coating) nanobelts anode shows its best comprehensive value: The initial Coulombic efficiency (CE) dramatically increases from 44% to 73% compared to bare MoO 3 electrode; It also delivers highest initial specific capacity of 1153.7 mAh g −1 at 100 mA g −1 , which is superior to the uncoated MoO 3 (427.3 mAh g −1 ). Additionally, MoO 3 @85-TiO 2 nanobelts show a remarkable long-life stability from initial 913.6 to 935.8 mAh g −1 after 400 charge-discharge cycles at 400 mA g −1 . The advanced TEM characterizations reveal that the TiO 2 layer can experience a transition from amorphous into crystalline Li 2 Ti 2 O 4 with cubic structure (a = 8.375 A) during cycling, which are acted as an efficient lithium ion conductor. Furthermore, the quantified mechanical properties demonstrate a remarkable decrease in the bending elastic modulus of MoO 3 @85-TiO 2 nanobelts compared to that of pristine MoO 3 . Therefore, the boosted electrochemical performance can be attributed to efficient lithium ions transportation across the moderate conductor layer and robust mechanical integrity that the large volume variation. These results advance the understanding in the coating regulated materials for enhanced-performance LIBs.
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