Mechanism of Anion-Catalyzed C–H Silylation Using TMSCF3: Kinetically-Controlled CF3-Anionoid Partitioning As a Key Parameter

Andrés García-Domínguez,Pedro H. Helou de Oliveira,Gilian T. Thomas,Arnau R. Sugranyes,Guy C. Lloyd Jones

Mechanism of Anion-Catalyzed C–H Silylation Using TMSCF3: Kinetically-Controlled CF3-Anionoid Partitioning As a Key Parameter

2021

Andrés García-Domínguez
Pedro H. Helou de Oliveira
Gilian T. Thomas
Arnau R. Sugranyes
Guy C. Lloyd Jones

The mechanism of anion-catalyzed C–H silylation by R3SiCF3 reagents has been investigated using homogeneous TBAT-initiation, in situ and stopped-flow 19F NMR spectroscopy 2H-KIE, LFER, deuterium-la...

Keywords:

Ion
Silanes
Catalysis
Taft equation
Reagent
Silylation
Polymer chemistry
Kinetics
Chemistry
Deprotonation

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