Poly[4,4′-iminodipyridinium [di-μ4-isophthalato-κ4O:O′:O′′:O′′-di-μ3-isophthalato-κ3O:O′:O′′;κ4O:O′:O′′,O′′′-trizinc(II)] dihydrate]
2008
In the title compound, {(C10H11N3)[Zn3(C8H4O4)4]·2H2O}n, divalent Zn atoms are linked into trinuclear units featuring tetrahedral, octahedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate dianions into [Zn3(isophthalate)4]n2n− anionic layers, which aggregate into the three-dimensional structure via hydrogen-bonding pathways mediated by doubly protonated 4,4′-iminodipyridinium cations and water molecules of crystallization. One solvent water molecule was found to be disordered over two positions, each with a 50% site-occupancy factor.
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