Flow-Electrode CDI Removes the Uncharged Ca–UO2–CO3 Ternary Complex from Brackish Potable Groundwater: Complex Dissociation, Transport, and Sorption

Unacceptably high uranium concentrations in decentralized and remote potable groundwater resources, especially those of high hardness (e.g., high Ca2+, Mg2+, and CO32– concentrations), are a common worldwide problem. The complexation of alkali earth metals, carbonate, and uranium(VI) results in the formation of thermodynamically stable ternary aqueous species that are predominantly neutrally charged (e.g., Ca2(UO2)(CO3)30). The removal of the uncharged (nonadsorbing) complexes is a problematic issue for many water treatment technologies. As such, we have evaluated the efficacy of a recently developed electrochemical technology, termed flow-electrode capacitive deionization (FCDI), to treat a synthetic groundwater, the composition of which is comparable to groundwater resources in the Northern Territory, Australia (and elsewhere worldwide). Theoretical calculations and time-resolved laser fluorescence spectroscopy analyses confirmed that Ca2(UO2)(CO3)30 was the primary aqueous species followed by Ca(UO2)(C...