[9,10-Dihydro-9,10-bis(trimethylsilyl)-9,10-anthrylen]magnesium; Molekülstruktur eines „Anthracenmagnesiums”
1985
Es werden die Darstellung und die Molekulstrukturen von 9,10-Bis(trimethylsilyl)anthracen (3) und dessen Reaktionsprodukt 5 mit Magnesiummetall beschrieben. In 5 uberbruckt Magnesium intramolekular die 9,10-Positionen eines 9,10-Dihydro-9,10-bis(trimethylsilyl)-anthrylen-Systems.
[9,10-Dihydro-9,10-bis(trimethylsilyl)-9,10-anthrylene]magnesium – Molecular Structure of an „Anthracene Magnesium”
The preparation and molecular structure of 9,10-bis(trimethylsilyl)anthracene (3) as well as of 5, the product of its reaction with metallic magnesium, are described. The magnesium atom in 5 forms an intramolecular bridge between the 9- and 10-positions of a 9,10-bis(trimethylsilyl)anthrylene system.
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