Highly Diastereoselective and Irreversible Aldol Reactions of N-Sulfonylimidates
2016
A mild method for the aldolization of N -sulfonylimidates was developed. The reaction proceeds in excellent diastereoselectivity to provide a range of useful β-hydroxyimidates in high yield. The innate reversibility of the reaction is suppressed by the use of a titanium complex as a Lewis acid.
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