Preparation of graphene oxide/poly(vinyl alcohol) composite membrane and pervaporation performance for ethanol dehydration

Although poly(vinyl alcohol) (PVA) membranes are widely used in solvent dehydration by pervaporation, the separation factor is rather limited. Considering this, novel PVA mixed matrix membranes with graphene oxide (GO) nanosheets were prepared. poly(acrylonitrile) ultrafiltration (PAN) membrane was used as support layer. The PVA/GO composite membranes were characterized by Fourier transform infrared spectroscopy, X-ray diffractometry, scanning electron microscopy, thermogravimetric analysis and water contact angle. We also explored the pervaporation performance of the membrane for ethanol dehydration. GO slightly improves the thermal stability and crystallinity of the composite membranes. In addition, the hydrophilicity of the composite membranes is weakened after GO addition, but the crosslinking degree is increased, resulting a significant increase in the separation factor and a certain decrease in the total flux. With the amount of GO addition increases, the total flux of the PVA/GO composite membrane decreases, while the separation factor increases first and then decreases, and the preferred amount of GO addition is 2.0 wt%. Especially, the separation factor of the composite membranes with 2.0 wt% GO addition could reach 3 059, which is 16 times higher than PVA membranes, with the corresponding permeability flux is 145 g m−2 h−1.