Synthesis of Quaternary Carbon Stereogenic Centers Through Enantioselective Cu‐Catalyzed Allylic Substitutions with Vinylaluminum Reagents.
2011
Catalytic enantioselective allylic substitution reactions using alkyl- and aryl-substituted vinylaluminum reagents afford 1,4-dienes containing a quaternary carbon stereogenic center at C-3, also by addition of a vinyl unit.
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