Enantioselective Aerobic Epoxidation of Acyclic Simple Olefins Catalyzed by the Optically Active β-Ketoiminato Manganese(III) Complex.
2010
Enantioselective aerobic epoxidation of acyclic cis-olefins into the corresponding optically active epoxides was carried out with good-to-high enantioselectivities by using a new class of optically active β-ketoiminato manganese(III) complex catalyst, N,N′-ethylenebis(α-mesitoyl-β-ketoiminato)manganese(III) chloride. The key intermediate of the present epoxidation is also discussed.
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