N‐(Trimethylsilyl)imidazole
2007
[18156-74-6] C6H12N2Si (MW 140.29)
InChI = 1S/C6H12N2Si/c1-9(2,3)8-5-4-7-6-8/h4-6H,1-3H3
InChIKey = YKFRUJSEPGHZFJ-UHFFFAOYSA-N
(silylating agent for alcohols1 and 1,3-dicarbonyl compounds;2 reaction with esters to give imidazolides; preparation of O-trimethylsilyl monothioacetals; aromatization of the a-ring of steroids)
Physical Data: bp 93–94 °C/14 mmHg; fp 5 °C; d 0.956 g cm−3.
Form Supplied in: liquid.
Handling, Storage, and Precautions: flammable. Harmful by inhalation, in contact with skin, and if swallowed. Possible carcinogen. Use in a fume hood. When using, wear protective gear and clothing. Handle and store under N2. Store in a cool dry place.
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