Chiral 2‐Cyano Esters as Synthetic Intermediates in the Synthesis of R and S α‐Methylvaline.
1995
Abstract A divergent stereoselective synthesis of R and S α-methylvaline from (2RS) (1S,2R,4R)-10-dicyclohexylsulfamoylisobornyl 2-cyano-3-methylbutanoate has been developed.
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