Fluorescent azadipyrrinato zinc(II) complex: hybridisation with a dipyrrinato ligand

Ryota Sakamoto,Shinpei Kusaka,Yasutaka Kitagawa,Masa-aki Kishida,Mikihiro Hayashi,Yusuke Takara,Mizuho Tsuchiya,Junko Kakinuma,Takuma Takeda,Keisuke Hirata,Tomoya Ogino,Keisuke Kawahara,Toshiki Yagi,Shu Ikehira,Tomoya Nakamura,Mayuko Isomura,Mikoto Toyama,Saki Ichikawa,Mitsutaka Okumura,Hiroshi Nishihara

Fluorescent azadipyrrinato zinc(II) complex: hybridisation with a dipyrrinato ligand

2012

We synthesised heteroleptic azadipyrrinato–dipyrrinato hybrid zinc(II) complex 1-Zn-2, by means of the stepwise coordination method. Homoleptic bis(azadipyrrinato)zinc(II) complex 1-Zn-1 was non-fluorescent, whereas 1-Zn-2 exhibited detectable fluorescence from azadipyrrinato ligand 1.

Keywords:

Zinc
Photochemistry
Homoleptic
Fluorescence
Chemistry
Inorganic chemistry
Ligand
Organic chemistry

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