Availability and interconnectivity of pores in mesostructured ZSM-5 zeolites by the adsorption and diffusion of mesitylene

Probing the mesopore architecture in mesoporous zeolites is of importance for large scale applications of the materials. In this work, the adsorption and diffusion of mesitylene with larger molecule size in mesoporous ZSM-5 zeolites were carried out, in order to acquaint the availability and interconnectivity of mesopores in zeolite crystals. The comparisons of the shape of adsorption isotherms and the mesopore volume calculated from mesitylene and N2 adsorption in mesoporous ZSM-5 zeolites with different mesoporosities can be used to discriminate two cases of mesopores: accessible mesopores connected to external surface of the zeolite crystals and non-accessible meso-voids that are occluded in the microporous matrix. Furthermore, the effective diffusivity and activation energy of mesitylene in mesoporous ZSM-5 extracted from ZLC desorption curves as a function of mesopore volume calculated from mesitylene adsorption reveal the enhancement of mesopore interconnectivity to molecule diffusion in zeolite crystals.