Synthesis and styrene copolymerization of novel trisubstituted ethylenes: 8. Halogen ring-disubstituted 2-methoxyethyl phenylcyanoacrylates
2021
Novel trisubstituted ethylenes, halogen ring-disubstituted
2-methoxyethyl phenylcyanoacrylates, RPhCH=C(CN)CO2CH2CH2OCH3 (where R is 2,5-dibromo, 3,5-dibromo, 2,3-dichloro, 2,4-dichloro, 2,6-dichloro,
3,4-dichloro, 3,5-dichloro, 2,4-difluoro, 2,5-difluoro, 2,6-difluoro, 3,4-difluoro,
3,5-difluoro, 2-chloro-6-fluoro, 3-chloro-4-fluoro, 2-chloro-5-nitro, 4-chloro-3-nitro,
2-fluoro-5-iodo) were
prepared and copolymerized with styrene. The ethylenes were synthesized by the
piperidine catalyzed Knoevenagel condensation of ring-substituted benzaldehydes
and 2-methoxyethyl cyanoacetate, and characterized by CHN analysis, IR, 1H
and 13C NMR. All the ethylenes were copolymerized with styrene in
solution with radical initiation (ABCN) at 70°C. The compositions of the copolymers were
calculated from nitrogen analysis.
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