Supramolecular Complexes between C‐undecylresorcinarene‐ Oligo(phenylenevinylene)‐Dendrimers and Fullerene C60

Dendritic branches of oligo(phenylenevinylene) were attached to a C‐undecylresorcinarene core. Two new supramolecular complexes were obtained between the dendrimers of first and second generation with the fullerene C60. The formation of the complexes 1:1 was confirmed by solid state 13C NMR spectroscopy. Strong π‐π, CH‐π, and n‐π interactions between the dendrimers and the fullerene C60 were detected in the supramolecular complexes by FTIR and 13C CP‐MAS NMR.