An Organocatalytic Cascade Approach toward Polysubstituted Quinolines and Chiral 1,4‐Dihydroquinolines–Unanticipated Effect of N‐Protecting Groups

Xinshuai Zhang,Xixi Song,Hao Li,Shilei Zhang,Xiaobei Chen,Xinhong Yu,Wei Wang

An Organocatalytic Cascade Approach toward Polysubstituted Quinolines and Chiral 1,4‐Dihydroquinolines–Unanticipated Effect of N‐Protecting Groups

2012

Xinshuai Zhang
Xixi Song
Hao Li
Shilei Zhang
Xiaobei Chen
Xinhong Yu
Wei Wang

The outcome of the aza-Michael/aldol cascade reaction of 2-aminobenzaldehydes or the corresponding ketones with ynals depends on the choice of the N-protecting group.

Keywords:

Organocatalysis
Cascade
Organic chemistry
Chirality (chemistry)
Cascade reaction
Aldol reaction
Photochemistry
Divergent synthesis
Chemistry
Sulfonyl
Triethylamine
Stereochemistry
Aromatization
Trimethylsilyl

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