Room temperature optically detected magnetic resonance (photoluminescence detected magnetic resonance) of radical ion pairs induced by vacuum ultraviolet in thin polymeric films

A setup for recording optically detected electron paramagnetic resonance spectra of radical ions involved in geminate recombination and generated by vacuum ultraviolet is described. The setup allows registration of EPR spectra from short-lived radical ions in polymeric films at room temperature by recombination fluorescence modulated by a resonance microwave field.