4-Pyridyl-9,9′-spirobifluorenes as Host Materials for Green and Sky-Blue Phosphorescent OLEDs
2015
We report herein new pyridine-substituted spirobifluorene (SBF) dyes, i.e., 4-(9,9′-spirobi[fluoren]-4-yl)pyridine (4-4Py-SBF), 3-(9,9′-spirobi[fluoren]-4-yl)pyridine (4-3Py-SBF), and 2-(9,9′-spirobi[fluoren]-4-yl)pyridine (4-2Py-SBF), built on the association of the 4-substituted spirobifluorenyl core and various regioisomers of pyridine. These organic semiconductors possess high triplet energy levels (ET around 2.7 eV) in accordance with their use as hosts for green and sky-blue phosphorescent organic light-emitting diodes (PhOLEDs). These dyes have been synthesized from the 4-bromo-spirobifluorene (4-Br-SBF) platform, obtained from a new and efficient synthetic approach using the promising building block 4-bromofluorenone as a key intermediate. Synthesis, structural, thermal, electrochemical, and photophysical properties of the three dyes have been investigated in detail and compared to other model compounds, namely, 4-phenyl-SBF (4-Ph-SBF), 2-phenyl-SBF (2-Ph-SBF), and 2,4-pyridyl-SBF (2-4Py-SBF), in ...
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