Hollow and Core–Shell Microgels at Oil–Water Interfaces: Spreading of Soft Particles Reduces the Compressibility of the Monolayer

We investigate the influence of a solid core and of the cross-link density on the compression of microgel particles at oil–water interfaces by means of compression isotherms and computer simulations. We investigate particles with different morphology, namely core–shell particles containing a solid silica core surrounded by a cross-linked polymer shell of poly(N-isopropylacrylamide), and the corresponding hollow microgels where the core was dissolved. The polymer shell contains different amounts of cross-linker. The compression isotherms show that the removal of the core leads to an increase of the surface pressure at low compression, and the same effect can be observed when the polymer cross-link density is decreased. Low cross-link density and a missing core thus facilitate spreading of the polymer chains at the interface and, at high compression, hinder the transition to close hexagonal packing. Furthermore, the compression modulus only depends on the cross-link density at low compression, and no differ...