Base-catalyzed Schmittel cycloisomerization of o-phenylenediyne-linked bis(arenol)s to indeno[1,2-c]chromenes
2013
Abstract We describe the transition metal-free base-catalyzed Schmittel cycloisomerization reactions of o -phenylene-linked bis(arenol)s to indeno[1,2- c ]chromene derivatives through prototropic rearrangement (tautomerization) to a putative vinylidene o -quinone methide intermediate with an enyne-allene system followed by a formal inverse-electron-demand hetero Diels–Alder cycloaddition. The preliminary results on catalytic asymmetric cycloisomerization with chiral bases are also disclosed.
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