Cs 2 ZnSn 3 S 8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure
2021
Birefringence, an important optical performance parameter for optoelectronic functional materials, is mainly influenced by the types of anion groups and their spatial arrangement. Inspired by the relationship between the structure and properties of chalcogenides, combined with the dimensional transformation, we successfully synthesized a sulfide compound (Cs2ZnSn3S8) with a two-dimensional layered structure and a large birefringence. The experimental results showed that, compared with Rb10Zn4Sn4S17, Cs2ZnSn3S8 achieved the structural transition from a zero-dimensional arrangement to a two-dimensional lamellar arrangement and achieved a breakthrough of birefringence from 0 to 0.12, which was determined by both experiments and first-principles calculations. These findings demonstrated that Cs2ZnSn3S8 was a potential birefringent material and provided instructions for the study of the synthesis of birefringent materials.
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