Orientational Isomerism and Binding Ability of Nonsymmetrical Guests Encapsulated in a Self‐Assembling Heterodimeric Capsule

The ability of a guest to induce the assembly of tetracarboxyl-cavitand 1 and tetra(3-pyridyl)-cavitand 2 into a heterodimeric capsule 1⋅2, and the orientational isomerism of nonsymmetrical p-disubstituted-benzene guests encapsulated in 1⋅2, are described. For example, the ability of a guest to induce the assembly of guest⊂(1⋅2) increases in the order p-iodoaniline≤p-chloroanisolebromoanisole

Keywords:

• Chemistry
• Organic chemistry
• Self-assembly
• Inorganic chemistry
• Atom
• Supramolecular chemistry
• Fluorine
• Substituent
• Halogen
• Tetra
• Capsule

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