New bacteriochlorin derivatives with a fused N-aminoimide ring
2003
Upon interaction of hydrazine hydrate with bacteriopurpurin, the initially formed monohydrazide in an acidic medium readily reacts with the second carboxyl group to give a six-membered N-aminocycloimide of bacteriochlorin p6. The free amino group at the fused imide ring makes it easy to obtain N-alkyl and N-acyl derivatives. The compounds thus obtained exhibit high light-induced cytotoxicity on A549 human adenocarcinoma cells.
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