Ultrafast Intramolecular Charge Separation in a Donor–Acceptor Assembly Comprising Bis(η5-cyclopentadienyl)molybdenum Coordinated to an Ene-1,2-dithiolate-naphthalenetetracarboxylicdiimide Ligand
2012
The first example of a Donor-spacer-Acceptor tryad, based upon a molybdenum-ene-1,2-dithiolate unit as the Donor and a naphthalene-diimide as the Acceptor, has been synthesized and its photophysical properties investigated. Synthesis required the preparation of a new pro-ligand containing a protected ene-1,2-dithiolate bound through a phenyl linkage to a naphthalenetetracarboxylicdiimide (NDI) group. Deprotection of this pro-ligand by base hydrolysis, followed by reaction with [Cp2MoCl2], produced the new dyad [Cp2Mo(SC(H)C(C6H4–NDI)S)] (2). Electrochemical studies showed that 2 can be reversibly oxidized to [2]+ and reduced to [2]−, [2]2–, and [2]3–. These studies, augmented by UV/vis, IR, and electron paramagnetic resonance (EPR) spectra of electrochemically generated [2]+ and [2]−, show that the highest occupied molecular orbital (HOMO) of 2 is ene-1,2-dithiolate-based and the lowest unoccupied molecular orbital (LUMO) is NDI-based; these conclusions are supported by density functional theory (DFT) cal...
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