Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers Through Copper‐Catalyzed Conjugate Additions of Aryl‐ and Alkylaluminum Reagents to Acyclic Trisubstituted Enones.

Jennifer A. Dabrowski,Matthew T. Villaume,Amir H. Hoveyda

Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers Through Copper‐Catalyzed Conjugate Additions of Aryl‐ and Alkylaluminum Reagents to Acyclic Trisubstituted Enones.

2013

Jennifer A. Dabrowski
Matthew T. Villaume
Amir H. Hoveyda

The title reaction allows a new, efficient, and widely applicable method to prepare ketones bearing an all-carbon quaternary stereogenic center at β position.

Keywords:

Conjugate
Copper
Carbon
Enantioselective synthesis
Stereocenter
Aryl
Chemistry
Organic chemistry
Reagent
Catalysis
copper catalyzed
quaternary carbon

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