Evidence of a Volcanogenic Massive Sulfide (ZnPbCuAg) district within the Tiébélé Birimian (Paleoproterozoic) Greenstone Belts, Southern Burkina Faso (West – Africa)

Abstract Twenty years after the discovery of the Perkoa Zn Ag deposit, another type of Zn Cu Pb ± Ag Volcanogenic Massive Sulfide (VMS) subgroup of occurrences forming a district has been highlighted within the Paleoproterozoic Birimian Greenstone Belts of the West African Craton in Burkina Faso. The geology of the area is characterized by a series of dominantly mafic volcanic rocks with intercalated black shales which increase in proportion upwards in the stratigraphy. This stratigraphic package is overlain by a felsic volcanic sequence comprising reworked tuff and rhyolite. Although mineralization is locally associated with sedimentary rocks, it is more commonly found in rhyolites. The metamorphic grade is dominantly greenschist facies. The main lithologies in the mafic sequence range from basalt to andesite with associated gabbro. The felsic sequence consists of dacite to rhyolite with associated granitoids (granite-granodiorite-tonalite). The volcanic rocks are commonly tholeiitic (Zr/Y = 2–4.5) with relatively high Zr and Y content, although a limited number of samples plot in transitional (Zr/Y = 4.5–7) or calc-alkaline (Zr/Y = 7–25) fields. Rhyolites, which constitute the main mineralized rocks at Tiebele, have similar key trace element signatures to other rhyolites-related known VMS systems worldwide. Both have low Zr/Y ( N /Yb N ( 2 . Typical mineral assemblages defining VMS occurrences are mainly hosted by meta-sedimentary rocks and rhyolite but are also found as veins in tonalite. These assemblages can be grouped into four different styles: (i) Variably banded massive sulfides dominated by sphalerite over galena, pyrite, and chalcopyrite within metasediments; (ii) Pyrite-rich or pyrrhotite banded type associated with sphalerite, chalcopyrite, and galena within silicified and carbonatized units; (iii) Disseminated and finely oriented sulfides, including pyrite – pyrrhotite – magnetite ± sphalerite within quartz-phyric rhyolite; and (iv) Fracture filling pyrrhotite-rich - magnetite - sphalerite mineralization possibly within tonalite. Irrespective of the style of the mineralization, chemistry of altered and least altered rhyolite reveals a significant increase in Mg ± Fe and H 2 O, and a loss of K within mineralization associated alteration. This may suggest sea water leaching of underlying (?) mafic and sedimentary rocks, with Mg Fe transfer into the rhyolites concomitant with the loss of K. This paper highlights the features of new occurrences of VMS mineralization type within the Birimian system of West Africa. We think this could help for new discoveries along the belts. Exploration based upon ground mapping, geochemistry and geophysics is highly recommended.