Detect, Remove and Re-use: Sensing and Degradation Pesticides via 3D Tilted ZMRs/Ag Arrays

Abstract The objective of this study was to design a versatile and reusable pesticide detection surface-enhanced Raman scattering (SERS) substrate in combination with SERS enhancement and self-cleaning properties. In this paper, we present an inexpensive way to synthesize three-dimensional tilted ZnO micron rods with an Ag hierarchical structure (ZMRs/Ag arrays). Although expensive materials and complex methods were not used, the detection limit of thiram residue was 10-11 M, with a quantitative relationship (R2 = 0.9929) between the thiram concentration and the intensity of the SERS peaks. Additionally, the substrates exhibited fast and efficient photocatalytic activity for the degradation of adsorbed thiram, and the degradation rate in 30 min was close 100% under visible-light irradiation. The enhancement and photocatalytic mechanism of this substrate were meticulously analyzed in detail. Furthermore, the residues of several mixed pesticides (e.g., thiram and methamidophos compounds) in various juices (such as grape, pear, orange, apple, and cherry juices) were quickly detected using ZMRs/Ag substrates. The main advantages of this substrate are recyclability, stability, selectivity, handiness, and cost-effectiveness. The substrate can prevent single-use problems associated with conventional SERS substrates and can be applied in pesticide residue and food security.