Modifying Surfaces with the Primary and Secondary Faces of Cyclodextrins To Achieve a Distinct Anti-icing Capability

Heterogenous ice nucleation (HIN) induced by organic materials is a long-lasting issue in wide-ranging fields from cryobiology to atmospheric physics, but efforts for controlling HIN are still restricted by incomplete understanding of its mechanism. In this work, distinct anti-icing capabilities were achieved by experimentally investigating the HIN behavior on the surfaces modified with the primary face (PF) and secondary face (SF) of cyclodextrins (CDs) (i.e., α-1,4-linked d-(+)-glucopyranose with two relatively flat and hydroxylated faces). To achieve this, CDs were first immobilized to the surfaces through selectively binding the PF and SF of CDs onto the solid surfaces; as such, either PF or SF is exposed to liquid water. Interestingly, HIN temperature and delay time assays indicate that HIN is depressed when the PF of CDs (which matches with the ice lattice) is exposed to liquid water whereas the HIN is facilitated when the SF of CDs (which mismatches with the ice lattice) is exposed to liquid water....