Blue Tetrakis(diisopropylamino)‐cyclo‐tetraborane and Yellow Tetrakis(tetramethylpiperidino)tetrabora‐tetrahedrane
1999
The colored boranescloso-1 and cyclo-2 are obtained upon dehalogenation of sterically hindered diaminodichlorodiborane(4) 3. The TMP groups of 1 cause the formation of a tetrahedrane, whereas in 2 the diisopropylamino substituents stabilize the bent four-membered ring. TMP=2,2,6,6-tetramethylpiperidino.
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