Di-μ-bromo-bis{aqua[(5-bromo-1H-imidazol-4-ylmethylene)(2-pyridylmethyl)amine-κ3N,N′,N′′]nickel(II)} dibromide
2006
In the title compound, [Ni2Br2(C10H9BrN4)2(H2O)2]Br2, the asymmetric unit consists of one half-cation and one Br− anion. The dinuclear cation is located on an inversion centre and each NiII ion is chelated by one tridentate (5-bromo-1H-imidazol-4-ylmethylene)(2-pyridylmethyl)amine (BIPI) ligand, one water molecule and two bridging Br− ligands. The tridentate BIPI ligand is essentially planar. Hydrogen bonds involving the Br− anions stabilize the crystal structure.
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KQI