Распределение молекул поверхностно-активных веществ в полимерном клубке

Interaction between ionomer and surfactant molecules in the low-polar organic solvents are studied. It is proposed that ionogenic groups as well as the surfactant molecules do not dissociate in the solution. The interaction of surfactant and polymer coil is described in the framework of mean field theory. Distribution of low-molecular surfactant concentration in the volume of a polymer coil is calculated. It is found that surfactant distribution in the macromolecule depends on the number of ionogenic groups in the polymer chain, thermodynamic quality of the solvent and surfactant concentration in solution. The equations describing the state of surfactant-ionomer complexes axe received.