Platinum Disulfide by XPS

It is known from crystallographic investigations that there are two distinct Pt–S modifications, PtS and PtS2 [see R. Collins, R. Kaner, P. Russo, A. Wold, and D. Avignant, Inorg. Chem. 18, 727 (1979); A. Finley, D. Schleich, J. Ackerman, S. Soled, and A. Wold, Mater. Res. Bull. 9, 1655 (1974); S. Soled, A. Wold, and O. Gorochov, ibid. 11, 927 (1976); L. Thomasson, Z. Phys. Chem. Bd. 2, 349; and L. Thomasson, ibid. 4, 277]. They are not commercially available in high grade purity. In the present study the production of pure PtS2 reference materials and its characterization by x‐ray photoelectron spectroscopy is presented. The PtS investigation is shown in a second submission. The PtS2 samples were produced by annealing stoichiometric mixtures of elemental platinum (DEGUSSA, grade 99.9%) and sulfur (Riedle de Haen, grade 99.5%). Both powders were blended homogeneously and pressed into pellets. The pellets were annealed for 3 weeks in an evacuated quartz tube (800 °C, 10−4 Pa) and cooled in defined steps to...