Application of polyurethane-based devices as sorption-desorption phases for microextraction analysis – The all-in-one microextraction concept

Abstract In this work, polyurethane-based (PU) devices having cylindrical geometry soaked with suitable organic solvents are proposed for microextraction analysis. This novel analytical approach (PU microextraction; PUμE) operates under the floating sampling technology for extraction, followed by mechanical compression using a manual syringe for back-extraction. To test the performance of the PUμE method, two series of priority contaminants were used as model compounds (group #1: metalaxyl-M, penconazole and tebuconazole; group #2: atrazine, terbuthylazine, alachlor and benzo[a]pyrene) and extracted from aqueous samples followed by gas chromatography-mass spectrometry (GC–MS) analysis. The preparation of the PUμE devices and the device handling procedures are described. Also, the optimization experiments as well as the application of the new method to real matrices are discussed. Assays performed on 25 mL water samples spiked at trace levels yielded average recoveries ranging from (50.1 ± 6.7) % to (93.3 ± 1.6) %, under optimized experimental conditions. The analytical performance showed good detection limits (0.01–0.50 μg/L) and linear dynamic ranges (0.1–50.0 μg/L) with acceptable determination coefficients ( r 2  > 0.9937). Excellent repeatability was also achieved in both intraday (RSD