Enantioselective Addition of Diethylzinc to Aldehydes in the Presence of Chiral Hydrazone and Imine Ligands.

Takashi Mino,Atsushi Suzuki,Masakazu Yamashita,Shusaku Narita,Yoshiaki Shirae,Masami Sakamoto,Tsutomu Fujita

Enantioselective Addition of Diethylzinc to Aldehydes in the Presence of Chiral Hydrazone and Imine Ligands.

2007

Takashi Mino
Atsushi Suzuki
Masakazu Yamashita
Shusaku Narita
Yoshiaki Shirae
Masami Sakamoto
Tsutomu Fujita

Optically active hydrazone and imine were found to act as effective ligands for enantioselective addition of diethylzinc to aldehydes. This reaction provided optically active secondary alcohols with ee up to 71%.

Keywords:

Imine
Enantioselective synthesis
Diethylzinc
Chirality (chemistry)
Hydrazone
Chemistry
Ligand
Organic chemistry
imine ligands

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