Synthesis and structure of N-heterocyclic carbene complexes of uranyl dichloride
2001
Treatment of UO2Cl2(thf)3 in
THF with two equivalents of 1,3-dimesitylimidazole-2-ylidene (IMes) or
1,3-dimesityl-4,5-dichloroimidazole-2-ylidene (IMesCl2) yields
novel monomeric uranyl N-heterocyclic carbene complexes,
representing the first examples of actinyl carbon bonds.
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