PolarizationControl of the Interface Ferromagnetic to Antiferromagnetic PhaseTransition in Co/Pb(Zr,Ti)O 3

Based on first-principles calculations, we predict the polarization control of the interfacial magnetic phase and a giant electronically driven magnetoelectric coupling (MEC) in Co/PbZr0.25Ti0.75O3 (PZT)(001). The effect of Co oxidation at the interface shared with (Zr,Ti)O2-terminated PZT is evidenced. The magnetic phase of the oxidized Co interface layer is electrically switched from the ferromagnetic to the antiferromagnetic state by reversing the PZT polarization from upward to downward, respectively. A comparative study between oxidized and unoxidized Co/PZT interfaces shows that in oxidized Co/PZT bilayers, the variation of the interface spin moment upon polarization reversal exceeds that of unoxidized Co/PZT bilayers by about 1 order of magnitude. We define a surface MEC constant αS taking into account the polarization dependence of both the spin and orbital moments. In unoxidized Co/PZT bilayers, we obtain αS ≈ 2 × 10–10 G cm2 V–1, while a giant surface coupling αS ≈ 12 × 10–10 G cm2 V–1 is found ...