Synthesis and Molecular Structure of Substituted 2-Hydroxyperhydro[1,3,2]dioxaborinino[5,4-c]pyridines, Perhydro[1,3]dioxano[5,4-c]pyridine, and Their Precursor — 4-Hydroxy-3-(α-hydroxybenzyl)-1-methyl-4-phenylpiperidine.
2009
4,8a-Diphenyl-substituted 2-(2-propoxy)perhydro[1,3,2]dioxaborinino[5.4-c]pyridine was obtained by the condensation of 4-hydroxy-3-(α-hydroxybenzyl)-1-methyl-4-phenylpiperidine with triisopropyl borate, and its 2-hydroxysubstituted analog in the presence of water. 1-Methyl-4,8a-diphenyl-perhidro[1,3]dioxano[5,4-c]pyridine was synthesized by the reaction of the same piperidol with formaldehyde. A comparative study of the molecular structures of the three products was carried out by X-ray crystallography.
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