Catalyst-Free Aminomethylamination of o-Hydroxystyrenes with Aminals to 1,3-Diamines
2018
A new catalyst-free protocol for aminomethylamination of o-hydroxystyrenes with simple aminals is described. This direct and operationally simple method provides a fundamentally novel and rapid approach for the synthesis of 1,3-diamines. This novel reaction occurs under mild reaction conditions and provides a fundamentally unique and efficient strategy for the synthesis of 1,3-diamines with good to excellent yields.
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