Iridium-Catalyzed γ‑Selective Hydroborationof γ‑Substituted Allylic Amides
2020
Reported here for the first time
is the Ir-catalyzed γ-selective
hydroboration of γ-substituted allylic amides under mild reaction
conditions. A variety of functional groups could be compatible with
reaction conditions, affording γ-branched amides in good yields
with ≤97% γ-selectivity. We have also demonstrated that
the obtained borylated products could be used in a series of C–O,
C–F, C–Br, and C–C bond-forming reactions.
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