A Molecular-Based Magnet with a Fully Interlocked Three-Dimensional Structure
1993
A compound has been synthesized with the formula (rad) 2 Mn 2 [Cu(opba)] 3 (DMSO) 2 .2H 2 O, where rad + is 2-(4- N -methylpyridinium)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, opba is orthophenylenebis(oxamato), and DMSO is dimethyl sulfoxide. It consists of two nearly perpendicular graphite-like networks with edge-sharing Mn(II) 6 Cu(II) 6 hexagons. The two networks are fully interlocked with the same topological relationship as that between adjacent rings of a necklace. The compound has three kinds of spin carriers: Mn(II) and Cu(II) ions, antiferromagnetically coupled through oxamato bridges, and rad + radical cations, bridging the Cu(II) ions through the nitronyl nitroxide groups and forming Cu-rad chains. The temperature dependence of the magnetization reveals that below 22.5 K, the compound behaves as a magnet.
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