Climatic implication of hydrogen isotope ratios of terrigenous n-alkanes in lacustrine surface sediment of the Tibetan Plateau

2008 
δD values of terrigenous n-alkanes (n-C25, n-C27, n-C29 and n-C31) extracted from recent lake surface sediments of Lake Qiangyong Glacier, Lake Kongmu Co, Lake Nam Co, Lake Keluke and Lake Xiao Qaidam along the S-N transect of Tibetan Plateau are compared to those of precipitation spanning a wide range from -167‰ to -51‰ and clearly correlate with δD values of meteoric water during the growth, indicating that terrigenous n-alkanes record the precipitation signal during the growth. The isotopic fractionation between precipitation and alkanes of n-C25 and n-C27 cover a range from -45‰ to -70‰ whilst that between precipitation and alkanes of n-C29 and n-C31 vary from -70‰ to -95‰, both being fairly constant along the S–N Tibetan transect with the mean at -57‰ and -82‰, respectively. By comparison with the apparent isotope fractionation of -130‰ along the S–N European transect, it implies that the apparent hydrogen isotopic fractionation between meteoric water and terrestrial n-alkanes along the Tibetan transect is much smaller.
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