Efficient Osmium/Rhenium-Catalyzed Dihydroxylation of Olefins with Hydrogen Peroxide under Acidic Conditions
2003
Simple addition of citric acid confers great stability to the catalytically active osmium and rhenium species involved in a triple catalytic system utilizing aqueous hydrogen peroxide as the terminal oxidant. The resulting system is capable of dihydroxylating traditionally resistant olefins in high yields.
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